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Alloy Steel F22 Round Bar

Alloy Steel F22 round bar (ASTM A182 Grade F22, UNS K21590) is a 2.25% chromium, 1% molybdenum creep-resisting steel supplied in Class 1 or Class 3. It combines creep strength to around 600 C with resistance to high-temperature hydrogen attack, making it the standard choice for hydroprocessing reactors and hot hydrogen piping.

➡️ F22 | UNS K21590 | EN 1.7380

➡️ ASTM, EN, JIS & International Standards

➡️ Supply Conditions

➡️ Multiple Diameters & Supply Lengths

➡️ Global Export & International Delivery

Alloy Steel F22 Round Bar Warehouse Image - Euro Steel Bars

Country of Origin:

Europe, Japan, USA

Material Type:

Alloy Steel

UNS Number:

K21590

Wr. No.:

1.7380

MTC Available:

EN 10204 3.1

Product Description for Alloy Steel F22 Round Bar

F22 is the ASTM A182 grade designation for a 2.25% chromium, 1% molybdenum low-alloy steel, UNS K21590. Bar is delivered against ASTM A182 / A182M with dimensions to ASTM A29 / A29M. The same alloy is P22 in ASTM A335 pipe and Grade 22 in ASTM A387 plate.

This is the backbone material of hydroprocessing and high-temperature refinery construction. The 2.00-2.50% chromium and 0.87-1.13% molybdenum combination gives good creep strength to around 600 C together with strong resistance to high-temperature hydrogen attack, which is why reactor vessels and hot hydrogen piping are built from it.

ASTM A182 defines F22 in Classes 1 and 3. Class 1 is the softer annealed condition at 415 MPa minimum tensile with hardness capped at 170 HBW. Class 3 is normalised and tempered at 515 MPa minimum tensile with a 156-207 HBW range.

Temper embrittlement is the defining concern with this alloy. Long exposure between roughly 340 C and 590 C causes phosphorus and other tramp elements to segregate to grain boundaries, raising the ductile-to-brittle transition temperature over years of service. Reactor work therefore controls residuals through the J-factor rather than relying on the standard limits alone.

The usual range is 10 mm to 300 mm. The steel is ferromagnetic and is not stainless.

Suitability for hydrogen service is judged against the Nelson curves in API 941 for the actual temperature and hydrogen partial pressure, not from the composition alone.

Typical work is hydroprocessing reactor internals, hot hydrogen piping hardware, valve and flange stock, and heater components.

Common Applications of Alloy Steel F22 Round Bar

➡️ Machined shafts, spindles, valve stems, pump sleeves and pins for food, beverage, dairy and pharmaceutical equipment, where the passive chromium oxide film resists both product acids and caustic clean-in-place chemicals.

➡️ Fasteners, studs, bolts, threaded rod and anchor components produced from bar stock, chosen for corrosion resistance combined with the ductility needed for cold heading and thread rolling.

➡️ Chemical, water treatment and general process plant parts such as agitator shafts, flange blanks, nozzles and support components handling water, steam and mildly corrosive media free of significant chlorides.

➡️ Architectural and structural hardware including handrail stanchions, balustrade fittings, tension rods and bollards, where a bright ground or polished bar finish provides both appearance and low maintenance.

International Equivalent Grade for Alloy Steel F22 Round Bar

Standard

Country / Region

Grade

ASTM A182 / A182M

USA

Grade F22 Classes 1 and 3 (UNS K21590)

ASTM A335 / A335M

USA

Grade P22 (seamless pipe)

ASTM A387 / A387M

USA

Grade 22 (plate)

EN 10216-2

Europe / EU

10CrMo9-10 (1.7380)

DIN 17175

Europe / EU

1.7380 (10CrMo9-10)

Table of Contents

Technical Specification for Alloy Steel F22 Round Bar

Specification

Value

Unit

Material

Alloy steel

-

Grade

F22 / UNS K21590 / 1.7380

-

Product Form

Round bar / rod

-

Standard

ASTM A182 / A182M Grade F22, Classes 1 and 3

-

Diameter

10 - 300 (typical supply range)

mm

Length

3 - 6 (random), or cut to length

m

Manufacturing Process

Hot rolled or forged, annealed or normalised and tempered

-

Production Route

EAF or BOF with ladle refining, vacuum degassing where residuals are controlled

-

Surface Finish

Hot-rolled, rough-turned, peeled, smooth-turned, centreless ground

-

Heat Treatment / Delivery Condition

Class 1 annealed, Class 3 normalised and tempered at 677 C minimum

-

Tolerance Standard

ASTM A29 / A29M

-

Density

7.80 (typical)

g/cm3

Melting Range

1425 - 1510 (typical)

C

Thermal Conductivity at 100 C

36.0 (typical)

W/m.K

Coefficient of Thermal Expansion (20-100 C)

12.4 (typical)

um/m.C

Specific Heat (0-100 C)

460 (typical)

J/kg.K

Electrical Resistivity at 20 C

0.22 (typical)

uOhm.m

Modulus of Elasticity at 20 C

205 (typical)

GPa

Magnetic Properties

Ferromagnetic in all conditions

-

Maximum Service Temperature

600 (typical, continuous)

C

Testing / Inspection Standard

ASTM A370 for mechanical testing, API 941 for hydrogen attack assessment

-

Certification / Inspection Documents

EN 10204 3.1 or 3.2 mill test certificate, J-factor reporting on request

-

Technical Specifications​ Icon

Technical Specifications

Get the key technical specifications for Alloy Steel F22 Round Bar

Material is ordered to ASTM A182 / A182M as Grade F22, with dimensional requirements from ASTM A29 / A29M. Class 1 is supplied annealed with hardness capped at 170 HBW. Class 3 is normalised and tempered at 677 C minimum, giving 515 MPa minimum tensile with a 156-207 HBW range. Composition is identical for both, so the class must be stated on the order.

Two service issues dominate this grade and neither is visible in the standard mechanical results.

The first is high-temperature hydrogen attack. At elevated temperature and hydrogen partial pressure, atomic hydrogen reacts with carbides inside the steel to form methane, which cannot diffuse out and creates internal fissures. Suitability is assessed against the Nelson curves in API 941 for the actual temperature and hydrogen partial pressure, not from the composition.

The second is temper embrittlement. Long exposure between roughly 340 C and 590 C drives phosphorus, tin, antimony and arsenic to grain boundaries, raising the ductile-to-brittle transition temperature over years. Reactor specifications therefore limit the J-factor, calculated from silicon, manganese, phosphorus and tin, typically to 100 or 150, well below what the standard chemistry limits alone would allow.

Welding needs preheat of roughly 200-300 C with mandatory post-weld heat treatment. Step cooling tests are commonly specified for reactor-grade material.

Chemical Composition for Alloy Steel F22 Round Bar

Element

Symbol

Min

Max

Unit

Carbon

C

0.05

0.15

%

Manganese

Mn

0.30

0.60

%

Silicon

Si

-

0.50

%

Phosphorus

P

-

0.040

%

Sulfur

S

-

0.040

%

Chromium

Cr

2.00

2.50

%

Molybdenum

Mo

0.87

1.13

%

Iron

Fe

Balance

-

%

Chemical Composition

View the chemical composition and applicable material limits for Alloy Steel F22 Round Bar

Chromium at 2.00-2.50% and molybdenum at 0.87-1.13% together produce the property that defines this grade: resistance to high-temperature hydrogen attack. Both are strong carbide formers, and the stable chromium and molybdenum carbides they create are far less readily reduced by atomic hydrogen than the iron carbides in plain carbon steel. That is what allows F22 to serve in hot hydrogen environments where leaner steels fissure internally.

The same carbides carry the creep strength, which is why the grade holds useful load-bearing capability to around 600 C.

Carbon is specified as a 0.05-0.15% range. The floor is needed for carbide formation, though carbon is deliberately kept modest, since more carbon means more carbide available to react with hydrogen.

Silicon is capped at 0.50% and manganese held to 0.30-0.60%. Both appear in the J-factor calculation used to assess temper embrittlement susceptibility, which is why reactor specifications often demand values well below these limits.

Phosphorus and sulphur are each permitted to 0.040% by the standard, but that is rarely the operative limit in practice. Phosphorus is the principal driver of temper embrittlement, and reactor-grade material is normally bought to far tighter residual controls covering tin, antimony and arsenic as well.

Mechanical Properties for Alloy Steel F22 Round Bar

Mechanical Property

Value

Unit

Tensile Strength, Class 1

415

MPa (minimum)

Tensile Strength, Class 3

515

MPa (minimum)

Yield Strength 0.2% Proof, Class 1

205

MPa (minimum)

Yield Strength 0.2% Proof, Class 3

310

MPa (minimum)

Elongation in 50 mm

20

% (minimum, both classes)

Reduction of Area, Class 1

35

% (minimum)

Reduction of Area, Class 3

30

% (minimum)

Hardness, Class 1

170

HBW (maximum)

Hardness, Class 3

156 - 207

HBW (specified range)

Modulus of Elasticity

205

GPa (typical)

Mechanical Properties​ Icon

Mechanical Properties

Check the key mechanical properties and performance requirements of Alloy Steel F22 Round Bar

ASTM A182 / A182M governs these for Grade F22, tested to ASTM A370, shown against class because the two classes differ substantially.

Class 1 is the annealed condition at 415 MPa minimum tensile and 205 MPa minimum proof strength, with hardness capped at 170 HBW as a maximum only. Class 3 is normalised and tempered at 515 MPa minimum tensile and 310 MPa minimum proof strength, with hardness specified as a 156-207 HBW range having both a floor and a ceiling. That difference in how hardness is expressed reflects the different delivery conditions.

For reactor and hot hydrogen service the room-temperature mechanical results are the least interesting part of the certificate. What matters is creep-rupture behaviour, assessed through ASME allowable stresses, resistance to high-temperature hydrogen attack per the API 941 Nelson curves, and long-term toughness after temper embrittlement.

Charpy impact testing at a specified temperature is routinely added as a supplementary requirement, and step cooling tests are common for reactor-grade material. A step cooling test simulates years of service exposure in the embrittling range and measures how far the transition temperature shifts, which no room-temperature test can reveal.

Dimension / Sizes for Alloy Steel F22 Round Bar

Dimension / Size

Value

Unit

Diameter

10 - 300

mm

Standard Length

3 - 6 (random / mill lengths)

m

Custom Length

Cut to length available on request

-

Diameter Tolerance

Per ASTM A29 / A29M, varies with size and finish

-

Length Tolerance

Per ASTM A29 / A29M or as agreed at order

-

Straightness Tolerance

Per ASTM A29 / A29M or as agreed at order

-

End Condition

Square cut, chamfered, or as ordered

-

Surface Finish

Hot-rolled, rough-turned, peeled, smooth-turned, centreless ground

-

Available Size Range

10 - 300, larger diameters by forging on enquiry

mm

Cut-to-Length Availability

Available

-

Dimensional Standard

ASTM A29 / A29M

-

Dimensions & Sizes

Explore available diameters, lengths, and dimensional requirements for Alloy Steel F22 Round Bar

Pricing for Alloy Steel F22 Round Bar

Round Bar Prices are generally quoted per kilograms or meters tonnes and can fluctuate with the global raw material and market prices. The final price will depend on a variety of factors, including the grade size, diameter, length, surface finish, the quantity and whether the bars are cut to length or in standard lengths.

For smaller quantities,  we can also quote per metre or per piece basis once the required dimensions have been confirmed. Container-loads or orders that are larger in size are typically priced per tonne, based upon the specifications required and the supply conditions.

Please provide your desired dimensions, grades, length number, and end for a current quote including the lead time applicable and details for certification.

Pricing

Get current Alloy Steel F22 Round Bar pricing based on size, quantity, grade, finish, and delivery requirements.

Why Choose Us

Euro Steel Bars is an international distributor, stockist and exporter of stainless round steel bars that cover carbon, stainless alloy, special grades. We stock a variety of sizes and grades. We guarantee every order with mill test certificates as well as full quality-assurance documentation. Our name speaks to our roots: European-sourced materials that is backed by the certificates and rigor that buyers from Asia as well as the Gulf and Africa are looking for.

Each bar we deliver is accompanied by EN 10204 3.1 mill test certificates as well as complete documentation of quality, so what you receive corresponds to what’s written in the documents. We carry a selection of sizes and grades ready for transport, and cut length upon the request of customers, which results in quicker lead times, whether you’re ordering just a one-off spec or a complete project tonnage.

We operate an actual wholesale business that is that is supported with an internationally-operated supply chain therefore we are able to serve fabricators sourcing one grade the same way in the same way as an EPC contractor who is placing a large order. Our clients include manufacturers, fabricators EPC construction companies, engineers oil and gas projects as well as construction companies. we design our inventory as well as documentation to show what buyers need to bring projects forward.

Our customers trust us across Qatar, Oman, Bahrain, Kuwait, Jordan, Malaysia, Singapore, Thailand, Taiwan, Turkey, Italy and South Africa. If you’re looking to source an Gulf energy project, or a construction project within Southeast Asia, you get the same quality of certified material, the exact documentation, and the exact delivery procedure.

Frequently Asked Questions

Everything you should be aware of regarding Alloy Steel F22 Round Bar from the grade and standards internationally, to the available sizes and finishes, requirements for manufacturing and application. This section will help buyers examine specifications and options for supply prior to making an inquiry or requesting a quote.
Round bar made to ASTM A182 / A182M Grade F22, a 2.25% chromium, 1% molybdenum low-alloy creep-resisting steel, UNS K21590. Supplied in Class 1 annealed or Class 3 normalised and tempered, it combines creep strength to around 600 C with resistance to high-temperature hydrogen attack. The same alloy is P22 in ASTM A335 pipe and Grade 22 in ASTM A387 plate.
At elevated temperature and hydrogen partial pressure, atomic hydrogen diffuses into steel and reacts with carbides to form methane. Methane cannot diffuse back out, so it builds pressure internally and creates fissures. The chromium and molybdenum carbides in F22 are far more stable against that reaction than the iron carbides in carbon steel. Suitability is assessed against the Nelson curves in API 941 for the actual conditions.
Long exposure between roughly 340 C and 590 C drives phosphorus, tin, antimony and arsenic to segregate at grain boundaries, which raises the ductile-to-brittle transition temperature over years of service. A reactor that was tough when built can be brittle at start-up temperatures decades later. It is controlled by limiting the J-factor, calculated from silicon, manganese, phosphorus and tin, typically to 100 or 150 for reactor work.
Class 1 is the annealed condition at 415 MPa minimum tensile and 205 MPa proof strength, with hardness capped at 170 HBW as a maximum. Class 3 is normalised and tempered at 677 C minimum, giving 515 MPa minimum tensile and 310 MPa proof strength, with hardness specified as a 156-207 HBW range. Composition is identical, so the class must be on the order.
ASTM A182 / A182M Grade F22 governs the material, with dimensional tolerance, straightness and surface condition from ASTM A29 / A29M rather than the stainless standard ASTM A484. In Europe the corresponding grade is 10CrMo9-10 (1.7380) under EN 10216-2 and the former DIN 17175. State the class and delivery condition on the order.
Class 1 requires 415 MPa minimum tensile and 205 MPa proof strength with hardness capped at 170 HBW. Class 3 requires 515 MPa minimum tensile and 310 MPa proof strength with a 156-207 HBW hardness range. Both require 20% minimum elongation. Reduction of area is 35% minimum for Class 1 and 30% minimum for Class 3. For reactor service, creep and post-embrittlement toughness matter far more than these figures.
Yes, with proper procedure. Preheat of roughly 200-300 C is required, interpass temperature must be maintained, and post-weld heat treatment is mandatory. For reactor work the weld metal is also controlled for residuals, using the X-bar factor calculated from phosphorus, antimony, tin and arsenic, because weld metal embrittles by the same mechanism as the base material. Procedures should be formally qualified.
Diameters typically run 10 mm to 300 mm, with larger sizes forged on enquiry. Mill lengths are 3 to 6 metres, random or cut to length, with tolerances to ASTM A29 / A29M. For reactor or hot hydrogen service, specify J-factor reporting, tightened residual limits and step cooling testing on the order, since none of these are covered by the standard chemistry limits alone.

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