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Alloy Steel F91 Round Bar

Alloy Steel F91 round bar (ASTM A182 Grade F91, UNS K90901) is modified 9Cr-1Mo steel with vanadium, niobium and controlled nitrogen additions. Normalised and tempered to a martensitic structure, it gives roughly double the creep strength of F22 at 600 C, serving supercritical boiler headers, steam piping and high-temperature valve components.

➡️ Grade 91 | UNS K90901 | EN 1.4903

➡️ ASTM, EN, JIS & International Standards

➡️ Supply Conditions

➡️ Multiple Diameters & Supply Lengths

➡️ Global Export & International Delivery

Alloy Steel F91 Round Bar Warehouse Image - Euro Steel Bars

Country of Origin:

Europe, Japan, USA

Material Type:

Alloy Steel

UNS Number:

K90901

Wr. No.:

1.4903

MTC Available:

EN 10204 3.1

Product Description for Alloy Steel F91 Round Bar

F91 is the ASTM A182 grade designation for modified 9% chromium, 1% molybdenum steel, UNS K90901, known throughout power generation as Grade 91. Stock is supplied to ASTM A182 / A182M with dimensions to ASTM A29 / A29M. The same alloy is P91 in ASTM A335 pipe and Grade 91 in ASTM A387 plate.

It is not a variant of F9. The additions of 0.18-0.25% vanadium, 0.06-0.10% niobium and controlled nitrogen at 0.030-0.070% produce fine, stable precipitates in a tempered martensitic matrix, and those precipitates give creep strength roughly double that of F22 at 600 C. That is what made supercritical and ultra-supercritical boiler design practical.

Bar is normalised at 1040-1080 C and tempered at 730-800 C. Both steps are mandatory and neither is negotiable. Hardness is controlled to a 190-248 HBW range.

The alloy is unforgiving of thermal mistakes. Heating above the lower transformation temperature without a full renormalising cycle produces untempered martensite. Under-tempering leaves the material brittle. Type IV cracking in the fine-grained heat-affected zone of welds is a well-documented long-term failure mode, which is why post-weld heat treatment control is so strict.

Sizes span 10 mm to 300 mm, hot-finished or cold-finished, random length or cut to order. The steel is ferromagnetic and is not stainless despite carrying 9% chromium.

Positive material identification on delivery is routinely specified, because F91 and F9 are visually identical and confusing the two has caused serious problems in power plant construction.

Typical work is supercritical boiler and steam header hardware, high-temperature piping components, valve bodies and hot bolting.

Common Applications of Alloy Steel F91 Round Bar

➡️ Machined shafts, spindles, valve stems, pump sleeves and pins for food, beverage, dairy and pharmaceutical equipment, where the passive chromium oxide film resists both product acids and caustic clean-in-place chemicals.

➡️ Fasteners, studs, bolts, threaded rod and anchor components produced from bar stock, chosen for corrosion resistance combined with the ductility needed for cold heading and thread rolling.

➡️ Chemical, water treatment and general process plant parts such as agitator shafts, flange blanks, nozzles and support components handling water, steam and mildly corrosive media free of significant chlorides.

➡️ Architectural and structural hardware including handrail stanchions, balustrade fittings, tension rods and bollards, where a bright ground or polished bar finish provides both appearance and low maintenance.

International Equivalent Grade for Alloy Steel F91 Round Bar

Standard

Country / Region

Grade

ASTM A182 / A182M

USA

Grade F91 (UNS K90901)

ASTM A335 / A335M

USA

Grade P91 (seamless pipe)

ASTM A387 / A387M

USA

Grade 91 (plate)

EN 10216-2

Europe / EU

X10CrMoVNb9-1 (1.4903)

DIN 17175

Europe / EU

1.4903 (X10CrMoVNb9-1)

Table of Contents

Technical Specification for Alloy Steel F91 Round Bar

Specification

Value

Unit

Material

Alloy steel

-

Grade

F91 / Grade 91 / UNS K90901 / 1.4903

-

Product Form

Round bar / rod

-

Standard

ASTM A182 / A182M Grade F91

-

Diameter

10 - 300 (typical supply range)

mm

Length

3 - 6 (random), or cut to length

m

Manufacturing Process

Hot rolled or forged, normalised and tempered

-

Production Route

EAF with ladle refining and vacuum degassing for nitrogen control

-

Surface Finish

Hot-rolled, rough-turned, peeled, smooth-turned, centreless ground

-

Heat Treatment / Delivery Condition

Normalised 1040-1080 C, tempered 730-800 C

-

Tolerance Standard

ASTM A29 / A29M

-

Density

7.77 (typical)

g/cm3

Melting Range

1425 - 1510 (typical)

C

Thermal Conductivity at 100 C

28.0 (typical)

W/m.K

Coefficient of Thermal Expansion (20-100 C)

11.0 (typical)

um/m.C

Specific Heat (0-100 C)

480 (typical)

J/kg.K

Electrical Resistivity at 20 C

0.60 (typical)

uOhm.m

Modulus of Elasticity at 20 C

215 (typical)

GPa

Magnetic Properties

Ferromagnetic in all conditions

-

Maximum Service Temperature

600 (typical, continuous, up to 650 in some applications)

C

Testing / Inspection Standard

ASTM A370 for mechanical testing, hardness verification mandatory

-

Certification / Inspection Documents

EN 10204 3.1 or 3.2 mill test certificate with heat treatment records

-

Technical Specifications​ Icon

Technical Specifications

Get the key technical specifications for Alloy Steel F91 Round Bar

Buy to ASTM A182 / A182M as Grade F91, with dimensional requirements from ASTM A29 / A29M.

The heat treatment is the material. Normalising at 1040-1080 C dissolves the vanadium and niobium carbonitrides and produces martensite on cooling. Tempering at 730-800 C then precipitates them as a fine, stable dispersion. Miss either step, or get the temperatures wrong, and the creep strength that justifies the alloy simply is not there, even though room-temperature tensile testing may still pass.

Hardness at 190-248 HBW is the practical check. Below 190 HBW the material has been over-tempered and the precipitates have coarsened. Above 248 HBW it has been under-tempered and retains brittle untempered martensite.

Three field problems are worth knowing. Local heating above the lower transformation temperature, from a careless flame cut or an uncontrolled preheat, forms fresh untempered martensite that only a full renormalise and temper will fix. Post-weld heat treatment below the specified range leaves brittle weld metal. And Type IV cracking, a creep failure in the fine-grained heat-affected zone, appears after years of service and has caused numerous header failures worldwide.

Positive material identification is routinely specified, since F91 and F9 look identical and are not interchangeable.

Chemical Composition for Alloy Steel F91 Round Bar

Element

Symbol

Min

Max

Unit

Carbon

C

0.08

0.12

%

Manganese

Mn

0.30

0.60

%

Silicon

Si

0.20

0.50

%

Phosphorus

P

-

0.020

%

Sulfur

S

-

0.010

%

Chromium

Cr

8.00

9.50

%

Molybdenum

Mo

0.85

1.05

%

Vanadium

V

0.18

0.25

%

Niobium

Nb

0.06

0.10

%

Nitrogen

N

0.030

0.070

%

Nickel

Ni

-

0.40

%

Aluminium

Al

-

0.02

%

Iron

Fe

Balance

-

%

Chemical Composition

View the chemical composition and applicable material limits for Alloy Steel F91 Round Bar

Vanadium at 0.18-0.25%, niobium at 0.06-0.10% and nitrogen at 0.030-0.070% are what separate this alloy from ordinary 9Cr-1Mo. Together they form fine vanadium and niobium carbonitrides that resist coarsening far better than chromium or molybdenum carbides do, and it is that stability under years of load at temperature which roughly doubles the creep strength against F22 at 600 C.

Nitrogen is a deliberate alloying element here, not a residual, and the narrow range matters. Too little and there is not enough carbonitride to strengthen. Too much and toughness suffers.

Aluminium is capped very low at 0.02% for a specific reason. Aluminium ties up nitrogen as aluminium nitride, which removes it from the carbonitride chemistry and quietly destroys the creep strength. A heat can meet every other requirement and still underperform if aluminium runs high.

Chromium at 8.00-9.50% provides oxidation and steam-side corrosion resistance, and molybdenum at 0.85-1.05% adds solid-solution strengthening.

Carbon at 0.08-0.12% is tightly controlled to balance martensite hardness against weldability.

Phosphorus at 0.020% and sulphur at 0.010% are far tighter than the older Cr-Mo grades, protecting creep ductility and weld integrity.

Mechanical Properties for Alloy Steel F91 Round Bar

Mechanical Property

Value

Unit

Tensile Strength

620

MPa (minimum)

Yield Strength 0.2% Proof

415

MPa (minimum)

Elongation in 50 mm

20

% (minimum)

Reduction of Area

40

% (minimum)

Hardness

190 - 248

HBW (specified range, mandatory)

Modulus of Elasticity

215

GPa (typical)

Mechanical Properties​ Icon

Mechanical Properties

Check the key mechanical properties and performance requirements of Alloy Steel F91 Round Bar

These figures are ASTM A182 / A182M requirements for Grade F91, tested to ASTM A370. Tensile, proof strength, elongation and reduction of area are minima. Hardness is a mandatory 190-248 HBW range, and for this grade it is the single most informative number on the certificate.

Below 190 HBW the material has been over-tempered. The fine vanadium and niobium carbonitrides have coarsened and the creep strength that justifies the alloy is compromised, even though room-temperature tensile results may still comfortably pass. Above 248 HBW the material has been under-tempered and retains untempered martensite, which is brittle and prone to cracking in service or during fabrication.

Room-temperature strength is only modestly above F9, at 620 MPa against 585 MPa minimum tensile. The reason to specify F91 lies entirely in creep, where its stress-rupture strength at 600 C is roughly double that of F22, which is what allowed supercritical steam conditions to become economic.

Design for elevated temperature runs on ASME BPVC allowable stresses for the grade, not the tensile figures shown here.

Charpy impact testing is commonly specified as a supplementary requirement, and heat treatment records should be requested with the certificate.

Dimension / Sizes for Alloy Steel F91 Round Bar

Dimension / Size

Value

Unit

Diameter

10 - 300

mm

Standard Length

3 - 6 (random / mill lengths)

m

Custom Length

Cut to length available on request

-

Diameter Tolerance

Per ASTM A29 / A29M, varies with size and finish

-

Length Tolerance

Per ASTM A29 / A29M or as agreed at order

-

Straightness Tolerance

Per ASTM A29 / A29M or as agreed at order

-

End Condition

Square cut, chamfered, or as ordered

-

Surface Finish

Hot-rolled, rough-turned, peeled, smooth-turned, centreless ground

-

Available Size Range

10 - 300, larger diameters by forging on enquiry

mm

Cut-to-Length Availability

Available

-

Dimensional Standard

ASTM A29 / A29M

-

Dimensions & Sizes

Explore available diameters, lengths, and dimensional requirements for Alloy Steel F91 Round Bar

Pricing for Alloy Steel F91 Round Bar

Round Bar Prices are generally quoted per kilograms or meters tonnes and can fluctuate with the global raw material and market prices. The final price will depend on a variety of factors, including the grade size, diameter, length, surface finish, the quantity and whether the bars are cut to length or in standard lengths.

For smaller quantities,  we can also quote per metre or per piece basis once the required dimensions have been confirmed. Container-loads or orders that are larger in size are typically priced per tonne, based upon the specifications required and the supply conditions.

Please provide your desired dimensions, grades, length number, and end for a current quote including the lead time applicable and details for certification.

Pricing

Get current Alloy Steel F91 Round Bar pricing based on size, quantity, grade, finish, and delivery requirements.

Why Choose Us

Euro Steel Bars is an international distributor, stockist and exporter of stainless round steel bars that cover carbon, stainless alloy, special grades. We stock a variety of sizes and grades. We guarantee every order with mill test certificates as well as full quality-assurance documentation. Our name speaks to our roots: European-sourced materials that is backed by the certificates and rigor that buyers from Asia as well as the Gulf and Africa are looking for.

Each bar we deliver is accompanied by EN 10204 3.1 mill test certificates as well as complete documentation of quality, so what you receive corresponds to what’s written in the documents. We carry a selection of sizes and grades ready for transport, and cut length upon the request of customers, which results in quicker lead times, whether you’re ordering just a one-off spec or a complete project tonnage.

We operate an actual wholesale business that is that is supported with an internationally-operated supply chain therefore we are able to serve fabricators sourcing one grade the same way in the same way as an EPC contractor who is placing a large order. Our clients include manufacturers, fabricators EPC construction companies, engineers oil and gas projects as well as construction companies. we design our inventory as well as documentation to show what buyers need to bring projects forward.

Our customers trust us across Qatar, Oman, Bahrain, Kuwait, Jordan, Malaysia, Singapore, Thailand, Taiwan, Turkey, Italy and South Africa. If you’re looking to source an Gulf energy project, or a construction project within Southeast Asia, you get the same quality of certified material, the exact documentation, and the exact delivery procedure.

Frequently Asked Questions

Everything you should be aware of regarding Alloy Steel F91 Round Bar from the grade and standards internationally, to the available sizes and finishes, requirements for manufacturing and application. This section will help buyers examine specifications and options for supply prior to making an inquiry or requesting a quote.
Round bar made to ASTM A182 / A182M Grade F91, modified 9% chromium, 1% molybdenum steel with vanadium, niobium and controlled nitrogen additions, UNS K90901. Known as Grade 91, it is normalised at 1040-1080 C and tempered at 730-800 C to a martensitic structure. Its creep strength at 600 C is roughly double that of F22, which is what made supercritical steam plant practical.
They are different materials despite the similar designation. F9 is plain 9Cr-1Mo with no micro-alloying, tempered to 179-217 HBW. F91 adds 0.18-0.25% vanadium, 0.06-0.10% niobium and controlled nitrogen, producing fine carbonitrides in a tempered martensitic matrix, with a 190-248 HBW range and tight tempering control. F91 has far higher creep strength, and the two must never be substituted.
Because it is the practical indicator that heat treatment was done correctly, and heat treatment is what creates the properties. Below 190 HBW the material has been over-tempered and the strengthening carbonitrides have coarsened, so creep strength is compromised even though tensile testing passes. Above 248 HBW it has been under-tempered and retains brittle untempered martensite. Both are rejectable.
A creep failure mechanism in the fine-grained heat-affected zone alongside welds in Grade 91. That narrow band experiences a thermal cycle which coarsens the strengthening precipitates locally, leaving a weaker strip that creeps faster than the surrounding material. Failures typically appear after years of service rather than immediately, and it has caused numerous steam header failures. Careful weld procedure and post-weld heat treatment control reduce but do not eliminate the risk.
ASTM A182 / A182M Grade F91 governs the material, with dimensional tolerance from ASTM A29 / A29M. The same alloy is P91 in ASTM A335 pipe and Grade 91 in ASTM A387 plate. In Europe it is X10CrMoVNb9-1 (1.4903) under EN 10216-2 and the former DIN 17175. Request heat treatment records with the certificate, since the normalising and tempering temperatures determine the properties.
ASTM A182 requires at least 620 MPa tensile strength, 415 MPa 0.2% proof strength, 20% elongation and 40% reduction of area, with hardness falling inside a mandatory 190-248 HBW range. Room-temperature strength is only modestly above F9, so these numbers understate the real difference, which lies entirely in creep-rupture performance at temperature.
Because aluminium combines with nitrogen to form aluminium nitride, and that removes nitrogen from the vanadium and niobium carbonitride chemistry which provides the creep strength. A heat can satisfy every other composition requirement and still underperform badly in creep if aluminium runs high. The 0.02% cap protects against this, and it is one of the least obvious but most important limits in the specification.
Diameters typically run 10 mm to 300 mm, with larger sizes forged on enquiry. Mill lengths are 3 to 6 metres, random or cut to length, with tolerances to ASTM A29 / A29M. Specify positive material identification on delivery, since F91 and F9 are visually identical and confusing them has caused serious problems in power plant construction.

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